Performance assessment of poly (methacrylic acid)/silver nanoparticles composite as corrosion inhibitor for aluminium in acidic environment
Journal of Adhesion Science and Technology
Corrosion Protection and Materials Research Laboratory, Department of Chemistry, University of Uyo, Uyo, Nigeria; Centre of Research Excellence in Corrosion, Research Institute, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia
This article reports the preparation of poly (methacrylic acid)/silver nanoparticles composite (PMAA/AgNPs) by in situ mixing of aqueous solutions of PMAA and 1 mM AgNO<inf>3</inf> with natural honey as reducing and stabilizing agent. The prepared PMAA/AgNPs composite was characterized by UV-vis spectroscopy, Fourier transformed infrared, X-ray diffraction and energy dispersive spectroscopy (EDS) while the morphology of the AgNPs in the composite was obtained by transmission electron microscopy (TEM). TEM results revealed that the AgNPs were spherical in shape. The performance of PMAA/AgNPs composite as anticorrosion material for Al in acidic environment was examined by electrochemical, weight loss methods, complemented by surface analysis characterization with scanning electron microscopy (SEM), EDS and water contact angle measurements. Results obtained indicate that PMAA/AgNPs composite is effective corrosion inhibitor for Al in an acid-induced corrosive environment. Inhibition efficiency increased with increase in composite concentration but decreased with rise in temperature. From potentiodynamic polarization results, PMAA/AgNPs composite is found to function as a mixed-type corrosion inhibitor. The adsorption of the composite onto Al surface was found to follow El-Awady et al. adsorption isotherm model. SEM, EDS and water contact angle results confirmed the adsorption of the composite on Al surface. © 2015 Taylor and Francis.
Adsorption; Aluminum; Composite materials; Contact angle; Corrosion; Electron microscopy; Energy dispersive spectroscopy; High resolution transmission electron microscopy; Nanoparticles; Scanning electron microscopy; Solutions; Surface analysis; Transmission electron microscopy; X ray diffraction; Acid corrosion; Adsorption isotherm model; Anti-corrosion materials; Corrosion inhibition; Energy dispersive spectroscopies (EDS); Performance assessment; Poly (methacrylic acid); Water contact angle measurement; Corrosion inhibitors