Department of Chemistry, University of Cape Town, Rondebosch, Cape Town, South Africa
Maqeda, L., Department of Chemistry, University of Cape Town, Rondebosch, Cape Town, South Africa; Makhubela, B.C.E., Department of Chemistry, University of Cape Town, Rondebosch, Cape Town, South Africa; Smith, G.S., Department of Chemistry, University of Cape Town, Rondebosch, Cape Town, South Africa
Abstract A series of fluorocarbon-containing salicylaldimine and iminophosphine Schiff base ligands and their Rh(I) complexes were synthesized. The synthesized ligands and complexes were characterized using different analytical and spectroscopic techniques including (1H, 13C{1H}, 31P{1H} and 19F{1H} NMR spectroscopy), FT-IR spectroscopy, mass spectrometry (ESI and EI), and elemental analysis. In addition, single crystal X-ray diffraction was also used for characterization for complexes 1 and 2. Consequently, the Rh(I) synthesized complexes were evaluated as catalyst precursors in the hydroformylation of 1-octene. The hydroformylation results showed that the iminophosphine and salicylaldimine-based catalyst precursors are active and selective under mild conditions, converting 1-octene to mostly aldehydes. © 2015 Elsevier Ltd. All rights reserved.