Department of Chemistry, Mangosuthu University of Technology, P.O. Box 12363, Jacobs 4026, South Africa; School of Chemistry, University of KwaZulu-Natal Westville Campus, Chiltern Hills, P. Bag X54001, Durban 4000, South Africa
Gounden, A.N., Department of Chemistry, Mangosuthu University of Technology, P.O. Box 12363, Jacobs 4026, South Africa; Jonnalagadda, S.B., School of Chemistry, University of KwaZulu-Natal Westville Campus, Chiltern Hills, P. Bag X54001, Durban 4000, South Africa
The ozone-initiated oxidation of 2-chloroethanol was followed by monitoring the consumption of the halogenated organic substrate. Gas chromatographic analysis of the ozonated products showed an increase in conversion from about 1 % after 3 h of ozone treatment to about 22 % after 12 h. The yields of major ozonated products identified and quantified namely acetaldehyde, acetic acid, and chloride ion increased proportionately as a function of ozone treatment time. The percent conversion of 2-chloroethanol in the presence of acetic acid or ethyl acetate were found to be higher than those under solvent-free conditions with similar products obtained. The use of activated charcoal during the ozonolyis of 2-chloroethanol showed a significant increase in the percent conversion of the substrate compared to solvent free ozonation. Based on the experimental findings, the overall mechanism for the reaction between 2-chloroethanol and ozone is described. © 2013 Springer Science+Business Media Dordrecht.
2-Chloroethanol; Chloride ions; Ethyl acetates; Organic substrate; Ozone treatment; Solvent free; Solvent free conditions; Acetaldehyde; Acetic acid; Chlorine compounds; Dechlorination; Ozonization; pH; Ozone; 2 chloroethanol; acetaldehyde; acetic acid; acetic acid ethyl ester; activated carbon; carboxylic acid; chloride ion; organic solvent; ozone; acetaldehyde; acetate; acetic acid; activated carbon; charcoal; dechlorination; experimental study; organic compound; ozone; reaction kinetics; substrate; article; dechlorination; electric conductivity; gas chromatography; oxidation; ozonation; ozonolysis; Charcoal; Ethylene Chlorohydrin; Models, Chemical; Ozone; Solvents; Water Pollutants, Chemical; Water Purification