Department of chemistry, Faculty of Science and Agriculture, University of Fort Hare, Private Bag X 1314, Alice, South Africa
Mkhohlakali, A.C., Department of chemistry, Faculty of Science and Agriculture, University of Fort Hare, Private Bag X 1314, Alice, South Africa; Ajibade, P.A., Department of chemistry, Faculty of Science and Agriculture, University of Fort Hare, Private Bag X 1314, Alice, South Africa
In the research on TiO2 nanocrystalline sensitization, ruthenium(II) complexes have received considerable attention in order to get efficient dyes for DSSCs. In this study, we report the synthesis of ruthenium(II) complexes formulated as [Ru(L1)(L2)(NCS)2], [Ru(L3)(L1)((NCS)2] where L1= 1,10-phenanthroline-4,7-disulphonic acid, L2= 2,2'-bipyridine-4,4'-dicarboxylic acid and L3 = 1,10-phenanthroline-2,9-dicarboxy aldehyde. The compounds were characterized by 1H-NMR, FTIR, UV-Vis and fluorescence spectroscopy. The complexes exhibited a broad metal-to-ligand charge transfer (MLCT) absorption bands in the range 510-531 nm and intense (π-π*) transitions between 240-380 nm. Some of these complexes showed emission maxima up to 680 nm. The compounds were used sensitizers to fabricate solar cells and an overall conversion efficiencies of 0.2-1.06 % under standard 1 sun 1.5 AM illumination (100 mWcm-2) with open circuit voltage 0.53, and 0.6, 0.48 V, short circuit current density up to 3.4 mAcm-2 and fill factor up to 0.6 were obtained. © 2015 The Authors.